Acta Crystallographica Section E

Structure Reports Online

Volume 59, Part 1 (January 2003)

metal-organic compounds

Acta Cryst. (2003). E59, m1-m2 [ doi:10.1107/S160053680202202X ]

Nitratotris(2,2,6,6-tetramethyl-3,5-heptadionato)hafnium(IV)

U. K. Urs, M. S. Dharmaprakash, S. A. Shivashankar and T. N. Guru Row

Abstract: The title compound, [Hf(C₁₁H₁₉O₂)₃(NO₃)], is a mixed-ligand MOCVD precursor. Hf has distorted square antiprismatic coordination. Of the six tert-butyl groups present, four are found to be disordered.