Acta Crystallographica Section E

Structure Reports Online

Volume 57, Part 9 (September 2001)

inorganic compounds


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Acta Cryst. (2001). E57, i75-i76    [ doi:10.1107/S1600536801012983 ]

Pentaamminenitrosylchromium(III) dichloride

H. Akashi, M. Mori and T. Shibahara

Abstract: The cation in the title compound, [Cr(NO)(NH3)5]Cl2, is distorted octahedral with a linear Cr-N-O moiety. The short Cr-N(nitrosyl) distance of 1.692 (7) Å indicates significant multiple bonding between these atoms. The Cr atom, the NO group and the N atom trans to NO have m2m symmetry and the remaining N and Cl atoms have m symmetry.

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