Acta Crystallographica Section E

Structure Reports Online

Volume 57, Part 9 (September 2001)

metal-organic compounds


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Acta Cryst. (2001). E57, m393-m395    [ doi:10.1107/S1600536801012843 ]

Two-dimensional network of C-H...Cl-Co hydrogen bonds in the structure of 1,1,4,4-tetraisopropylpiperazinium tetrachlorocobaltate(II)

A. H. Mahmoudkhani, V. Langer and B. M. Casari

Abstract: The reaction of (2-hydroxyethyl)diisopropylammonium chloride with CoCl2·6H2O has resulted in the unusual formation of a quaternary piperazinium salt with the formula (tippipz)[CoCl4], where tippipz is tetraisopropylpiperazinium (C16H36N22+). The structure of this compound consists of sheets of organic ammonium dications and inorganic dianions formed by C-H...Cl hydrogen bonds.

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