Acta Crystallographica Section E

Structure Reports Online

Volume 57, Part 9 (September 2001)

metal-organic compounds

Acta Cryst. (2001). E57, m404-m406 [ doi:10.1107/S1600536801012788 ]

(Methanol){-5,10,15:-20-tetrakis[2-(chloroacetamido)phenyl]porphyrin}zinc(II) chloroform solvate

D. Ricard, P. Richard and B. Boitrel

Abstract: The pentacoordinated Zn atom in the title compound, [Zn(C₅₂H₃₆Cl₄N₈O₄)(CH₄O)]·CHCl₃, is displaced from the porphyrin N₄ plane towards the axial methanol ligand by 0.269 (2) Å. The average Zn-N(porphyrin) distance is 2.063 (9) Å and the axial Zn-O(MeOH) distance is 2.147 (5) Å.