Acta Crystallographica Section E

Structure Reports Online

Volume 57, Part 7 (July 2001)

metal-organic compounds


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Acta Cryst. (2001). E57, m308-m309    [ doi:10.1107/S1600536801008741 ]

trans-Dichlorobis(triphenylphosphine)nickel(II) bis(dichloromethane) solvate: redetermination at 120 K

A. S. Batsanov and J. A. K. Howard

Abstract: Re-investigation of [NiCl2(PPh3)2]·2CH2Cl2 at 120 K yielded much more accurate geometric parameters than the earlier room temperature study and confirmed the main conclusion of the latter: the Ni-P and Ni-Cl bonds in this centrosymmetric square-planar complex [2.2439 (5) and 2.1672 (5) Å] are significantly shorter than in the tetrahedral solvent-free [NiCl2(PPh3)2].

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