Acta Crystallographica Section B

Structural Science

Volume 56, Part 1 (February 2000)

research papers

Acta Cryst. (2000). B56, 2-10 [ doi:10.1107/S0108768199008927 ]

Neutron powder diffraction study of orthorhombic and monoclinic defective silicalite

G. Artioli, C. Lamberti and G. L. Marra

Abstract: The crystal structure of silicalite (SiO₂) with a substantial amount of structural hydroxyl groups [Si_(1-x)O_(2-4x)(OH)_4x, with 0.08 < x < 0.10] has been refined from neutron powder diffraction data measured using the HRPD instrument at the ISIS pulsed neutron source. Powder data were collected on the as-synthesized orthorhombic sample at 298 K, and on the deuterated monoclinic sample at 100 K. Preferential location of Si-atom vacancies was found on four out of 12 independent T sites in the orthorhombic silicalite [Si(6), Si(7), Si(10) and Si(11)], although the H atoms of the substituting hydroxyl groups could not be located because of the low statistical site occupancy on multiple sites. No significant population of D atoms or of Si vacancies was found in the tetrahedral sites of the monoclinic sample. The detected long-range order of adjacent Si atoms in defective orthorhombic [MFI] structures is compatible with a mechanism of Si vacancy clustering and with the model of hydroxyl nests assumed in the literature on the basis of IR spectroscopic evidence. Crystal data: orthorhombic, Pnma, Z = 8, a = 20.0511 (1), b = 19.8757 (1), c = 13.36823 (9) Å, V = 5327.62 (5) Å³, D_x = 1.798 g cm^-3, M_r = 721.01; monoclinic, P2₁/n, Z = 4, a = 19.8352 (2), b = 20.0903 (2), c = 13.3588 (1) Å, [beta] = 90.892 (1)°, V = 5322.78 (6) Å³, D_x = 1.799 g cm^-3, M_r = 1442.02.

Keywords: silicalite; orthorhombic; monoclinic; powder diffraction.