Acta Crystallographica Section B

Structural Science

Volume 58, Part 3 Number 2 (June 2002)

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Acta Cryst. (2002). B58, 471-476    [ doi:10.1107/S0108768102001052 ]

Crystal and electronic structure of a new metallic modification of (ET)2[KHg(SCN)4]

O. N. Kazheva, E. Canadell, G. G. Aleksandrov, N. D. Kushch and O. A. Dyachenko

Abstract: A new room-temperature metallic modification of the well known radical cation salt (ET)2[KHg(SCN)4] has been prepared by electrochemical oxidation of ET. Its crystal and electronic structure have been examined at 110 K. The salt has a layered structure in which the conducting layers are characterized by the [delta]-type packing.

Keywords: organic conductors; X-ray crystal structure; band structure.

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