Acta Crystallographica Section C

Crystal Structure Communications

Volume 64, Part 3 (March 2008)

metal-organic compounds


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Acta Cryst. (2008). C64, m121-m122    [ doi:10.1107/S0108270107044952 ]

[mu]2-Acetato-[kappa]2O:O'-tris([mu]2-ferrocenecarboxylato-[kappa]2O:O')bis[(N,N-dimethylformamide-[kappa]O)copper(II)]

J.-H. Luo, C.-C. Huang, X.-H. Huang and J.-G. Wang

Abstract: The title compound, [Cu2Fe3(C5H5)3(C2H3O2)(C6H4O2)3(C3H7NO)2], belongs to the classic dimeric paddle-wheel structure type. It is an unusual example in that it contains two different carboxylate groups, viz. ferrocenecarboxylate and acetate. With three ferrocenecarboxylate groups and only one acetate group bridging the two Cu centres, a noncentrosymmetric molecular arrangement results.

Formula: [Cu2Fe3(C5H5)3(C2H3O2)(C6H4O2)3(C3H7NO)2]

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