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13 citations found for Robinson, V.

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Acta Cryst. (2011). A67, C23
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The glycolytic enzyme enolase associates with the endoribonuclease RNase E in Escherichia coli and many other bacterial species. The crystal structure of the complex reveals the basis for the molecular recognition and provides clues as to the possible function of the interaction.


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The title compound, C14H21BrO3, comprises a seven- (C7) and three six-membered (1 × O2C4 and 2 × C6) rings, and each adopts a conformation based on a chair. Stability to the mol­ecular structure is afforded by an intra­molecular O—H...Br hydrogen bond. In the crystal structure, mol­ecules are arranged into a helical supra­molecular chain along the b axis, linked by C—H...O inter­actions, where the O-atom acceptor is one of the dioxane O atoms. The crystal studied was found to be a racemic twin. The major component was present 94% of the time.

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The cyclo­hexyl ring in the title compound, C12H15ClO2Se, has a chair conformation with the 4-hydr­oxy group occupying an axial position; the other non-H substituents occupy equatorial positions. Mol­ecules aggregate via O—H...O hydrogen bonds into a supra­molecular helical chain.

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In the title compound, C13H22O4, the acetonide ring adopts an envelope conformation with one of the O atoms as the flap atom, whereas a twisted conformation is found for the furan­ose ring. Centrosymmetric eight-membered {...OCOH}2 synthons involving the hydr­oxy H and acetonide O atoms are found in the crystal structure. These are linked into a supra­molecular chain in the a-axis direction via C—H...O contacts.

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The title compound (systematic name: 3,4-dihydr­oxy-3-phenyl­furan-2-one), C10H10O4, features a five-membered γ-lactone ring with an envelope conformation at the C atom carrying the hydr­oxy group without the phenyl substituent. In the crystal, supra­molecular chains mediated by O—H...O hydrogen bonding are formed along the a-axis direction. These are consolidated in the crystal structure by C—H...O contacts.

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The title compound, C13H16O, comprises two fused five-membered rings. Each ring has an envelope conformation, with the ether O atom in the furan­ose ring, and the CMe2 atom in the acetonide ring as the flap atoms. In the crystal, centrosymmetrically related mol­ecules associate via hydr­oxy–ether O—H...O hydrogen bonds and the resulting dimers are linked into a supra­molecular chain with a flattened topology via C—H...Ohydr­oxy contacts, and aligned in the a-axis direction.


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The experimental models of dicotyledonous cytoplasmic and plastid-located glutamine synthetases unveil a conserved eukaryotic-type decameric architecture, with subtle structural differences in M. truncatula isoenzymes that account for their distinct herbicide resistance.

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