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8 citations found for Hagen, K.

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A method enabling the retrieval of thickness or projected electron density of a sample from a single input image is derived theoretically and successfully demonstrated on experimental data.

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Acta Cryst. (2018). A74, a406
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The title compound, [Fe(C7H5O2)2(CH4O)4], is a centrosymmetric six-coordinate FeII complex coordinated by two axial monodentate benzoate ligands and four methanol ligands in the equatorial plane [Fe-Obenzoate 2.0935 (7) Å, and Fe-Omethanol 2.1310 (7) and 2.1290 (7) Å]. The benzoate ligands adopt monodentate ligation, rather than a bridged polymeric structure, because of strong intra- and intermolecular hydrogen bonds to the methanol ligands. This structure is nearly identical to that obtained with a much bulkier carboxyl­ate ligand [Chavez, Que & Tolman (2001). Chem. Commun. pp. 111-112].

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The crystals of the title compound, {[Co(en)2(MeCN)]2(μ-O2)}(CF3SO3)4 or [Co2(O2)(C2H3N)2(C2H8N2)4](CF3O3S)4, are built of binuclear tetracations and tri­fluoro­methane­sulfonate anions. The cation occupies a special position on the inversion center; the separation between the Co atoms, which have a slightly distorted octahedral coordination, is 4.4966 (7) Å, with Co—N(MeCN), Co—O, and average Co—N(en) distances of 1.938 (2), 1.8736 (17), and 1.950 Å, respectively. Both aceto­nitriles are trans to the O—O bridge, the O—O distance being 1.496 (3) Å. The [Co(en)2] moieties have δδ and the inversion-related λλ conformations.

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X-ray phase-contrast microtomography is demonstrated using two-dimensional amplitude modulation of the beam. The implementation is characterised in terms of angular sensitivity and spatial resolution, and its application to the three-dimensional imaging of biological soft tissues is shown.

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The title compound, C48H60O8·3C3H7NO, is a derivative of calix­[4]­arene in the cone conformation, modified with distal carboxylic acid functional groups at the lower rim. A clathrate di­methyl­form­amide (DMF) mol­ecule is located within the calix­[4]­arene cone, and two DMF solvate mol­ecules participate in hydrogen bonding with the carboxylic acid groups. Intramolecular hydrogen bonds are also formed between the OH groups and the adjacent ether groups in the partially substituted calix­[4]­arene.

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