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4 citations found for Dolmella, A

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The air-stable title compound was obtained by heating liquid acetyl­acetone with solid tri­phenyl­bismuth and was recrystallized from benzene. The product has two symmetry-equivalent but essentially identical mol­ecules in the asymmetric unit, both showing an intramolecular O-H...O hydrogen bond.



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The structure of the studied adduct consists of two dimethyl sulfoxide mol­ecules coordinating the [C2O4(SnPh3)2] core via their oxygen atoms. The Sn atoms display a trans trigonal–bipyramidal [SnC3O2] arrangement, and the oxalate dianion behaves as a bidentate bridging ligand.

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